Char and soot represent distinct types of elemental carbon (EC) with varying sources and physicochemical properties. However, quantitative studies in sources, atmospheric processes and light-absorbing capabilities between them remain scarce, greatly limiting the understanding of EC's climatic and environmental impacts. For in-depth analysis, concentrations, mass absorption efficiency (MAE) and stable carbon isotope were analyzed based on hourly samples collected during winter 2021 in Nanjing, China. Combining measurements, atmospheric transport model and radiative transfer model were employed to quantify the discrepancies between char-EC and soot-EC. The mass concentration ratio of char-EC to soot-EC (R-C/S) was 1.4 +/- 0.6 (mean +/- standard deviation), showing significant dependence on both source types and atmospheric processes. Case studies revealed that lower R-C/S may indicate enhanced fossil fuel contributions, and/or considerable proportions from long-range transport. Char-EC exhibited a stronger light-absorbing capability than soot-EC, as MAE(char) (7.8 +/- 6.7 m(2)g(-1)) was significantly higher than MAE(soot) (5.4 +/- 3.4 m(2)g(-1))(p < 0.001). Notably, MAE(char) was three times higher than MAE(soot) in fossil fuel emissions, while both were comparable in biomass burning emissions. Furthermore, MAE(soot) increased with aging processes, whereas MAE(char) exhibited a more complex trend due to combined effects of changes in coatings and morphology. Simulations of direct radiative forcing (DRF) for five sites indicated that neglecting the char-EC/soot-EC differentiation could cause a 10 % underestimation of EC's DRF, which further limit accurate assessments of regional air pollution and climate effects. This study underscores the necessity for separate parameterization of two types of EC for pollution mitigation and climate change evaluation.

Seasonal freezing and thawing significantly influence the migration and distribution of soil hydrothermal salts. Understanding the dynamics of hydrothermal salt forces in canal foundation soils is crucial for effective canal disease control and optimization. However, the impact on rectangular canals remains poorly understood. Therefore, field-scale studies on water-heat-salt-force-displacement monitoring were conducted for the canal. The study analyzed the changes and interaction mechanisms of water-heat-salt-force in the soil beneath the canal, along with the damage mechanisms and preventive measures. The results indicate that the most rapid changes in temperature, moisture, and salt occur in the subsoil on the canal side, with the greatest depth of freezing. Heat transfer efficiency provides an intuitive explanation for the sensitivity of ground temperature at the junction of the canal wall and subsoil to air temperature fluctuations, as well as the minimal moisture migration in this region under the subcooling effect. The temperature-moisture curve suggests that current waterheat-force and water-heat-salt-force models exhibit a delay in accurately predicting water migration within the subsoil. Rectangular canals are more susceptible to damage under peak freezing conditions, requiring a combined approach of freezing restraint and frost-heaving force to mitigate damage. These findings offer valuable insights for canal design, maintenance, and further research.

Carbonaceous aerosols play a crucial role in air pollution and radiative forcing, though their light-absorbing and isotopic characteristics remain insufficiently understood. This study analyzes optical absorption and isotopic composition in PM10 and PM2.5 particles from primary emission sources, focusing on traffic-related and solid fuel categories. We analyzed key optical properties, including the Angstrom absorption exponent (AAE), the contributions of black carbon (BC) and brown carbon (BrC) to total light absorption and the mass absorption efficiencies (MAE) of carbonaceous aerosols. AAE values were lower for traffic emission sources (0.9 to 1.3) than solid fuel emission sources (1.5 to 3), with similar values for both particle sizes. BrC contributions were more prominent at shorter wavelengths and were notably higher in solid fuel emission sources (61% to 88%) than in traffic emission sources (8% to 40%) at 405 nm. MAE values of BC at 405 nm were 2 to 20 times higher than BrC across different emissions. Particle size significantly affect MAE(BC) with PM2.5 higher when compared to PM10. Emissions from diesel concentrate mixer and raw coal burning exhibited the highest MAE(BC) for PM2.5 and PM10, respectively. Conversely, Coke had the lowest MAE(BC) but the highest MAE(BrC) for both sizes. Traffic emissions showed more stable carbon isotope ratios (delta C-13) enrichment (-29 parts per thousand to -24 parts per thousand) than solid fuels (-31 parts per thousand to -20 parts per thousand). delta C-13 of solid fuel combustion, unlike traffic sources, is found to be independent of size variation. These findings underscore the importance of source and size-specific aerosol characterization for unregulated emission sources.

Surface soil moisture (SSM) is a key limiting factor for vegetation growth in alpine meadow on the Qinghai-Tibetan Plateau (QTP). Patches with various sizes and types may cause the redistribution of SSM by changing soil hydrological processes, and then trigger or accelerate alpine grassland degradation. Therefore, it is vital to understand the effects of patchiness on SSM at multi-scales to provide a reference for alpine grassland restoration. However, there is a lack of direct observational evidence concerning the role of the size and type of patches on SSM, and little is known about the effects of patches pattern on SSM at plot scale. Here, we first measured SSM of typical patches with different sizes and types at patch scale and investigated their patterns and SSM spatial distribution through unmanned aerial vehicle (UAV)-mounted multi-type cameras at plot scale. We then analyzed the role of the size and type of patchiness on SSM at both patch and plot scales. Results showed that: (1) in situ measured SSM of typical patches was significantly different (P < 0.01), original vegetation patch (OV) had the highest SSM, followed by isolate vegetation patch (IV), small bare patch (SP), medium bare patch (MP) and large bare patch (LP); (2) the proposed method based on UAV images was able to estimate SSM (0-40 cm) with a satisfactory accuracy (R-2 = 0.89, P < 0.001); (3) all landscape indices of OV, with the exception of patch density, were positively correlated with SSM at plot scale, while most of the landscape indices of LP and IV showed negative correlations (P < 0.05). Our results indicated that patchiness intensified the spatial heterogeneity of SSM and potentially accelerated the alpine meadow degradation. Preventing the development of OV into IV and the expansion of LP is a critical task for alpine meadow management and restoration.

This paper establishes a novel full-process numerical simulation framework for analyzing the 3D seismic response of mountain tunnels induced by active faults. The framework employs a two-step approach to achieve wavefield transmission through equivalent seismic load: first, a highly efficient and accurate FMIBEM (Fast multipole indirect boundary element method) is used for large-scale 3D numerical simulations at the regional scale to generate broadband ground motions (1-5 Hz) for specific sites; subsequently, using the FEM (Finite element method), a refined simulation of the plastic deformation of surrounding rock and the elastoplastic behavior of the tunnel structure was conducted at the engineering scale. The accuracy of the framework has been validated. To further demonstrate its effectiveness, the framework is applied to analyze the impact of different fault movement mechanisms on the damage to mountain tunnels based on a scenario earthquake (Mw 6.7). By introducing tunnel structure damage classification and corresponding damage indicators, the structural damage levels of tunnels subjected to active fault movements are quantitatively evaluated. The findings demonstrate that the framework successfully simulates the entire process, from fault rupture and terrain amplification to the seismic response of tunnel structures. Furthermore, the severity of tunnel damage caused by different fault types is ranked as follows: reverse fault > normal fault > strike-slip fault.

The bank protection measures of waterways shall become more environmentally friendly in the future including the use of plants instead of stones. The low levels of protection provided by plants in the early phase after planting requires a process-based understanding of soil-wave-interaction. One process that is considered essential is liquefaction where the soil undergoes a phase-change from solid-like to fluid-like behaviour which could reduce the safety of the system. The aim of this publication is to analyse the results of column experiments on wave-induced soil liquefaction and to develop a numerical model which is able to describe the entire process from the pre-liquefaction phase to the following reconsolidation in order to support the analysis of liquefaction experiments. Numerical simulations of the column experiments were done using a fully coupled hydro-mechanical model implemented in the open-source software FEniCS. A permeability model derived from granular rheology allows the simulation of dilute as well as dense suspensions and sedimented soil skeletons. The results of the simulations show a good agreement with the experimental data. Theoretical limits in the liquefied state are captured without the common modelling segmentation into pre-and post-liquefaction phase. Due to the modular structure of the implementation, the constitutive setting can be adjusted to incorporate more complex formulations in order to study the influence of wall friction and non-linearity in soil behaviour.

Hurricane Otto caused sequential changes in tropical soil microbiota over 5 years.Acidobacteria were critical early decomposers of deposited canopy debris for 3 years.Complex C degrading fungi were critical later decomposers of debris starting at 4 years.A suite of C, N and microbial indicators should prove valuable for forest managers.Hurricanes cause significant damage to tropical forests; however, little is known of their effects on decomposition and decomposer communities. This study demonstrated that canopy debris deposited during Hurricane Otto stimulated sequential changes in soil carbon (C) and nitrogen (N) components, and decomposer microbial communities over 5 years. The initial response phase occurred within 2 years post-hurricane and appeared associated with decomposition of the labile canopy debris, suggested by: increased DNA sequences (MPS) of the Acidobacterial community (as common decomposers of labile plant material), decreases in total organic C (TOC), increased biomass C, respiration, and NH4+, conversion of organic C in biomass, and decreased MPS of complex organic C decomposing (CCDec) Fungal community. After 3 years post-hurricane, the later response phase appeared associated with decomposition of the more stable components of the canopy debris, suggested by: increased MPS of the Fungal CCDec community, TOC, stabilized Respiration, decreased Biomass C, the return to pre-hurricane levels of the conversion of organic C to biomass, and decreased MPS of Acidobacterial community. These changes in the microbial community compositions resulted in progressive decomposition of the hurricane-deposited canopy material within 5 years, resulting several potential indicators of different stages of decomposition and soil recovery post-disturbance.

The pedunculate oak (Quercus robur L.) is a major tree species in Europe, but it has faced recent growth decline and dieback events in some areas resulting in economic and ecosystem losses. In the southeastern edge of its natural distribution in eastern Romania, rising temperatures since the 1980s, when a shift towards warmer and more arid conditions occurred, increased evaporative demand and triggered growth decline. We analyzed the adaptive potential of six oak stands (333 individual trees) with ages ranging between 97 and 233 years, located in three wet and three dry sites. Results showed unstable climate-growth correlations with a breakpoint after 1985 when climate warming intensified. Wet soil conditions from early spring to summer enhanced growth; on the contrary, a high evaporative demand linked to warmer conditions and greater potential evapotranspiration reduced growth, particularly in wet sites. After 1985, drought stress induced a reduction in latewood width in dry sites. The relationship between growth and summer-autumn drought intensified during the last decades in all sites. Warmer spring conditions negatively affected oak growth, particularly latewood production. Wet sites had lower resilience indices, and we also noted a post-1985 progressive reduction of growth resilience. Slow-growing trees from dry sites showed growth decline, which could be an early-warning signal of impending dieback and tree death. In contrast, fast-growing trees from wet sites showed sustained relative growth improvement, which was attributed to tree age and size effects. After 1985, the pedunculate oak is more vulnerable to drought damage in dry sites near the southeastern distribution limit in response to hotter winter-spring droughts.

Soil-rock mixtures (SRMs) are characterized by heterogeneous structural features that lead to multiscale mechanical evolution under varying cementation conditions. However, the shear failure mechanisms of cemented SRMs (CSRMs) remain insufficiently explored in existing studies. In this work, a heterogeneous threedimensional (3D) discrete element model (DEM) was developed for CSRMs, with parameters meticulously calibrated to examine the role of matrix-block interfaces under different volumetric block proportions (VBPs). At the macroscopic scale, significant influences of the interface state on the peak strength of CSRMs were observed, whereas the residual strength was found to be largely insensitive to the interface cementation properties. Pronounced dilatancy behaviour was identified in the postpeak and residual phases, with a positive correlation with both interface cementation and VBP. Quantitative particle-scale analyses revealed substantial heterogeneity and anisotropy in the contact force network of CSRMs across different components. A highly welded interface was shown to reduce the number of interface cracks at the peak strength state while increasing the proportion of tensile cracks within the interface zone. Furthermore, the welding degree of the interface was found to govern the formation and morphology of shear cracking surfaces at the peak strength state. Nevertheless, a reconstruction method for the shear slip surface was proposed to demonstrate that, at the same VBP, the primary roughness of the slip surfaces remained consistent and was independent of the interface properties. Based on the extended simulations, the peak strength of the weakly welded CSRMs progressively decreased with increasing VBP, whereas further exploration of the enhanced residual strength is needed.

Submarine landslides are a geological hazard that may cause significant damage, and are among the most serious problems in offshore geotechnics. Understanding the mechanism of submarine landslide/offshore structure interaction is essential for risk assessment, but it is challenging due to its complexities. In this study, ten centrifuge tests were conducted to determine how offshore wind turbines founded on four piles respond to consecutive submarine landslides. The tests highlighted two mechanisms of soil deformation and foundation settlement associated with the landslide cycle: (1) deformations of the clay were associated with induced excess pore water pressure, and increased with the number of landslides; and (2) by contrast, foundation settlements largely depended on the dynamic impact of the first cycle and remained unchanged for the remaining events. The settlements were 0.5 m for the 10 m pile foundation and about 0.1 m for the 20 m pile foundation, both in clay and in sand. It was also found that increasing pile length reduces the excess pore water pressure, soil deformation and foundation settlement.