The Three-Rivers Headwater Region (TRHR) is located on the Tibetan Plateau, within a transitional zone between seasonally frozen ground and continuous permafrost. Over 70 % of the region is predominantly covered by alpine grasslands, a vulnerable ecosystem increasingly threatened by ongoing permafrost degradation. This study utilized satellite data to analyze permafrost degradation by measuring active layer thickness (ALT) and the soil non-frozen period (NFP), and to investigate their impacts on alpine grassland growth. Results showed significant permafrost degradation from 2000 to 2020, with ALT thickening at a rate of 7.79 cm/decade (p < 0.05) and NFP lengthening by 1.1 days/yr (p < 0.05). Simultaneously, grassland vegetation exhibited a significant greening trend (0.0014 yr(-1), p < 0.01). Using the partial least squares (PLS) regression method, the study evaluated the relationships between grassland dynamics and permafrost degradation, while jointly accounting for climate variables (temperature, precipitation, and sunshine duration). ALT thickening was the dominant explanatory variable for grassland growth in 11.09 % of the region, and it was positively correlated in relatively cold western and alpine areas, but negatively correlated in the relatively warm eastern and central regions. NFP extension was the dominant explanatory variable for grassland growth in 10.38 % of the region, although its positive correlation weakened as climate conditions transitioned from relatively cold-dry to relatively warm-wet. Although permafrost degradation was positively correlated with grassland greening in relatively cold regions, the diminishing benefit of NFP extension and the adverse effects of ALT thickening may increasingly undermine grassland stability in relatively warm regions under further climate warming.

The reasonable value of good gradation characteristic parameters is key in designing and optimising soil-rock mixed high fill embankment materials. Firstly, the DJSZ-150 dynamic-static large-scale triaxial testing instrument was used for triaxial compression shear tests on compacted skeleton structure soil-rock mixture standard specimens. The changes in strength and deformation indicators under different gradation parameters and confining pressure were analysed. Then, based on the Janbu empirical formula, relationships between parameters K, n, and (sigma 1-sigma 3)ult and the coefficient of uniformity Cu and coefficient of curvature Cc were explored. Empirical fitting formulas for Duncan-Chang model constants a and b were proposed, establishing an improved Duncan-Chang model for soil-rock mixtures considering gradation characteristics and stress states. Finally, based on significant differences in particle spatial distribution caused by gradation changes, three generalised models of matrix-block stone motion from different particle aggregation forms were proposed. Results indicate the standard specimen's strength and deformation indicators exhibit significant gradation effects and stress-state correlations. The improved Duncan-Chang model effectively simulates the stress-strain relationship curve under different gradations and confining pressure, with its characteristics explainable based on the matrix block stone motion generalised model.

Most gravel roads leading to rural areas in Ghana have soft spot sections as a result of weak lateritic subgrade layers. This study presents a laboratory investigation on a typical weak lateritic subgrade soil reinforced with non-woven fibers. The objective was to investigate the strength characteristic of the soil reinforced with non-woven fibers. The California Bearing Ratio and Unconfined Compressive Strength tests were conducted by placing the fibers in single layer and also in multiple layers. The results showed an improved strength of the soil from a CBR value of 7%. The CBR recorded maximum values of 30% and 21% for coconut and palm fibers inclusion at a placement depth of H/5 from the compacted surface. Multiple fiber layer application at depths of H/5 & 2 h/5 yielded CBR values of 38% and 31% for coconut and palm fibers respectively. The Giroud and Noiray design method and the Indian Road Congress design method recorded reduction in the thickness of pavement of 56% to 63% for coconut fiber inclusion and 45% to 55% for palm fiber inclusion. Two-way statistical analysis of variance (ANOVA) showed significant effect of depth of fiber placement and fiber type on the geotechnical characteristics considered. (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic),(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic),CBR(sic)(sic)7%(sic),(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)H/5(sic)(sic)(sic)(sic)(sic)(sic),CBR(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)30%(sic)21%. (sic)H/5(sic)2H/5(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic),(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)CBR(sic)(sic)(sic)(sic)38%(sic)31%. Giroud&Noiray(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)56%(sic)63%,(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)45%(sic)55%. (sic)(sic)(sic)(sic)(sic)(sic)(ANOVA)(sic)(sic),(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic).

In highway construction across the southeastern coastal regions of China, granite residual soil is widely used as subgrade fill material in pavement engineering. Its mechanical behaviour under dynamic loads warrants in-depth investigation. Dynamic events such as vehicular traffic and earthquakes are complex, involving multidirectional loads. The dynamic behaviour of soil under bidirectional cyclic loading differs significantly from that under cyclic loading in one direction. A large-scale bidirectional cyclic direct shear apparatus was utilised to carry on a series of horizontal cyclic direct shear tests on granite residual soil with water contents of 14% and 24% at different normal stress amplitudes (sigma a) (0, 100, 200 kPa). Based on these tests, discrete element method (DEM) models were developed to simulate the laboratory tests. The test results revealed that cyclic normal stress increases dynamic shear strength during forward shear but reduces it during reverse shear. The energy dissipation capacity increases with rising sigma a. The dynamic behaviour of granite residual soil is more significantly affected by cyclic normal stress when the water content is higher. The DEM simulation results indicated that as cyclic shearing progresses, the location of the maximum principal stress (sigma 1) shifts from the top of the specimen toward the shear interface. The distribution of the angle between sigma 1 and the x-axis, as well as sigma 1 and the z-axis, transitions from 'M' distribution to 'Arch' distribution. With increasing sigma a, during forward shear, the magnitude of the maximum principal stress increases, and the orientation of sigma 1 rotates toward the normal direction. Conversely, during reverse shear, the magnitude of the maximum principal stress decreases, and its orientation shifts toward the horizontal shear direction. The material fabric anisotropy coefficient decreases with increasing sigma a, while the anisotropy orientation increases with increasing normal stress.

The morphology of sheep wool applied as organic fertilizer biodegraded in the soil was examined. The investigations were conducted in natural conditions for unwashed waste wool, which was rejected during sorting and then chopped into short segments and wool pellets. Different types of wool were mixed with soil and buried in experimental plots. The wool samples were periodically taken and analyzed for one year using Scanning Electron Microscopy (SEM) and Energy-dispersive X-ray Spectroscopy (EDS). During examinations, the changes in the fibers' morphology were observed. It was stated that cut wool and pellet are mechanically damaged, which significantly accelerates wool biodegradation and quickly destroys the whole fiber structure. On the contrary, for undamaged fibers biodegradation occurs slowly, layer by layer, in a predictable sequence. This finding has practical implications for the use of wool as an organic fertilizer, suggesting that the method of preparation can influence its biodegradation rate. (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(SEM)(sic)(sic)(sic)(sic)(sic)X(sic)(sic)(sic)(sic)(EDS)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic).

Correlations between the mechanical properties and surface scratch resistance of polylactic acid (PLA) are investigated via tensile and scratch tests on samples after degradation in soil for various times. The results show that the tensile yield strength of PLA is inversely proportional to the natural logarithm of the degradation time, and the scratch resistance and fracture toughness of PLA and the temperature rise near the indenter all increase and then decrease. The surface crystallinity of PLA also increases and then decreases, indicating that it and the scratch resistance are closely related. These findings provide useful information about how PLA behaves under degradation conditions. (c) 2025 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC) license (https://creativecommons.org/licenses/by-nc/4.0/).

Understanding soil organic carbon (SOC) distribution and its environmental controls in permafrost regions is essential for achieving carbon neutrality and mitigating climate change. This study examines the spatial pattern of SOC and its drivers in the Headwater Area of the Yellow River (HAYR), northeastern Qinghai-Xizang Plateau (QXP), a region highly susceptible to permafrost degradation. Field investigations at topsoils of 86 sites over three summers (2021-2023) provided data on SOC, vegetation structure, and soil properties. Moreover, the spatial distribution of key permafrost parameters was simulated: temperature at the top of permafrost (TTOP), active layer thickness (ALT), and maximum seasonal freezing depth (MSFD) using the TTOP model and Stefan Equation. Results reveal a distinct latitudinal SOC gradient (high south, low north), primarily mediated by vegetation structure, soil properties, and permafrost parameters. Vegetation coverage and above-ground biomass showed positive correlation with SOC, while soil bulk density (SBD) exhibited a negative correlation. Climate warming trends resulted in increased ALT and TTOP. Random Forest analysis identified SBD as the most important predictor of SOC variability, which explains 38.20% of the variance, followed by ALT and vegetation coverage. These findings likely enhance the understanding of carbon storage controls in vulnerable alpine permafrost ecosystems and provide insights to mitigate carbon release under climate change.

An analytical methodology was developed for the first time in this work enabling the simultaneous enantiomeric separation of the fungicide fenpropidin and its acid metabolite by Capillary Electrophoresis. A dual cyclodextrin system consisting of 4 % (w/v) captisol with 10 mM methyl-beta-cyclodextrin was employed in a 100 mM sodium acetate buffer at pH 4.0. Optimal experimental conditions (temperature 25 degrees C, separation voltage -25 kV, and hydrodynamic injection of 50 mbar x 10 s) allowed the simultaneous separation of the four enantiomers in <10.7 min with resolutions of 3.1 (fenpropidin) and 3.2 (its acid metabolite). Analytical characteristics of the method were evaluated and found adequate for the quantification of both chiral compounds with a linearity range from 0.75 to 70 mg L-1, good accuracy (trueness included 100 % recovery, precision with RSD<6 %), and limits of detection and quantification of 0.25 and 0.75 mg L-1, respectively, for the four enantiomers. No significant differences were found between the concentrations determined and labelled of fenpropidin in a commercial agrochemical formulation. The stability over time (0-42 days) of fenpropidin enantiomers using the commercial agrochemical formulation was evaluated in two sugar beet soils, revealing to be stable at any time in one sample, while in the other a decrease of 45 % was observed after 42 days. Individual and combined toxicity of fenpropidin and its metabolite was determined for the first time for marine organism Vibrio fischeri, demonstrating higher damage caused by parent compound. Synergistics and antagonists' interactions were observed at low and high effects levels of contaminants.

Global warming results in more field soil suffering freeze-thaw cycles (FTCs). The environmental risk of microplastics-recognized as a global emerging contaminant-in soils undergoing FTCs remains unclear. In this study, the combined effects of FTCs and poly(butylene adipate-co-terephthalate) (PBAT) microplastics on microbial degradation of atrazine in Mollisols were investigated. Freeze-thaw cycles, rather than microplastics, significantly inhibited the biodegradation of atrazine in soil, with average inhibition ratios of 33.69% and 4.99% for FTCs and microplastics, respectively. Thawing temperature was the main factor driving the changes in soil microbial community structures and the degradation of atrazine. The degradable microplastics with an amendment level of 0.2% had different and limited effects on the dissipation of atrazine under different modes of FTCs. Among the four modes, microplastics only showed a trend toward promoting atrazine degradation under high-frequency and high-thawing-temperature FTCs. Across all modes, microplastics altered microbial interactions and ecological niches that included affecting specific bacterial abundance, module keystone species, microbial network complexity, and functional genes in soil. There's no synergistic effect between microplastics and FTCs on the degradation of atrazine in soil within a short-term period. This study provides critical insights into the ecological effects of the new biodegradable mulch film-derived microplastics in soil under FTCs.

Aeolian sand, as a primary medium of desertification, changes surface energy budgets and consequently affects both ecological systems and infrastructure stability on the Tibetan Plateau. Accurate interpretation of upper boundary conditions is critical for assessing aeolian sand's effects on subsurface hydrothermal processes. Nevertheless, current numerical simulations typically rely on empirical thermal boundaries and neglect surface radiation components and latent heat exchange, causing, significant deviations between simulations and field observations. This study establishes a thermal boundary model to calculate net surface energy (Q) based on energy balance theory and 13 sets of reflectance experiments. Using meteorological data from 2003 to 2019, soil temperature evolution was simulated under three aeolian sand coverage conditions: dry, 5 % moisture, and 10 % moisture. Results indicated that the simulated outputs exhibit strong correlations with observed data in terms of trend direction, phase timing of peaks and troughs, and temperature amplitude (R > 0.93, p < 0.0001). At the sand-atmosphere interface (-0.05 m), the annual mean temperature under dry aeolian sand cover reached 5.300 degrees C, which is 4.823 degrees C higher than that of the exposed surface (0.477 degrees C) during 2005-2006. When including moisture, the latent heat-driven cooling effect became evident, and the annual mean temperature at the sand surface dropped significantly to 0.930 degrees C (5 % moisture) and 1.461 degrees C (10 % moisture). More importantly, moisture cooling effects in shallow layers (-0.05 to-0.4 m) exhibit non-monotonic behavior: 10 % moisture yields higher annual mean temperatures than 5 % moisture (e.g., 1.370 degrees C vs. 0.858 degrees C at-0.2 m), suggesting aeolian sand's thermal impact on underlying permafrost involves critical moisture thresholds.