This study aimed to improve the tribological properties of polytetrafluoroethylene (PTFE) in atmospheric and vacuum environments at high temperatures. A diamond-like carbon (DLC) coating was deposited on the PTFE substrate by sputtering. Tribological tests revealed that DLC-coated PTFE exhibited lower wear rates than uncoated PTFE in all experimental conditions. The dominant factor affecting tribological behavior was the amount and coverage of transfer film formed on the counter surface. DLC-coated PTFE exhibited higher transfer film coverage (~19.5% in atmospheric, ~18% in vacuum) than uncoated PTFE (~12% and ~14%, respectively). This enhancement was due to the high adhesion between the dangling carbon bonds in the transfer film of the DLC coating and the dangling carbon bonds in the PTFE produced by defluorination.
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